Unexpected Radical Telomerisation of Vinylidene Fluoride with 2-Mercaptoethanol

Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene

The radical copolymerisation in solution of vinylidene fluoride (or 1,1-difluoroethylene (VDF)) with hexafluoropropylene (HFP) initiated by di-tert-butyl peroxide is presented. A series of eight copolymerisation reactions was investigated with initial [VDF]o/[HFP]o molar ratios ranging from 5.0/95.0 to 85.2/14.8. Both co-monomers copolymerised in this range of copolymerisation. Moreover, only V...

Random and Sequential Radical Cotelomerizations of 3,3,3-Trifluoropropene (H2C=CHCF3) with Vinylidene Fluoride (F2C=CH2)

The synthesis of original co-telomers based on 3,3,3-trifluoropropene (TFP) and vinylidene fluoride (VDF) with a general formula: RF-[CH2-CF2]n-[CH2-CH(CF3)]m-I (where n=1-63, m=2-640, and RF=(CF3)2CF) was achieved by sequential and random cotelomerizations in the presence of RFI. The radical cotelomerizations were initiated by thermal decomposition of different peroxide and persulfate initiato...

Multiferroic tunnel junctions with poly(vinylidene fluoride)

Quantum Modelling of Poly(vinylidene Fluoride)

Copolymerization of vinylidene fluoride with 4-bromo-1,1,2-trifluoroethylene

The radical copolymerization of vinylidene fluoride (VDF) with 4-bromo-1,1,2-trifluorobut-